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Re: [Orchid] About heat hardening silver...
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Peter W. Rowe Thursday, November 16, 2000
   
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>        Peter, What is the "desired range" for heat hardening?  I have
>     experimented with using the cleaning cycle on my oven to do a
>     couple of different things.  Most ovens hit 800 to 850 degrees
>     during the cycle.  

    Morris, The Handy and Harmon "handy book" states a temperature of 600
    F, for 30-50 minutes.  I'll confess that in my prior post, I had it in
    my head that it was 700, not 600.  If your oven reaches 550, I'd bet
    that this will do the trick, though slower than 600 would.  

    If the cleaning cycle is reaching 850, though, then I think that at
    that point you're maybe getting uncomfortably close to the annealing
    range.  Now, I'm not a metallurgist, so I can only go on the temps I
    see published.  I don't know for sure at what point precipitation
    hardening stops and annealing starts instead. But I guess I'd opt for
    the lower temperature range instead, or at least test em both and see
    which works better.  

    Also, the handy book suggests that for the highest hardness, you want
    to initially anneal the silver at a much hotter than normal
    temperature, like up to 1375, for 15 minutes, followed by a water
    quench.  what that does is to both dissolve the copper rich phase
    (sterling is a mix of copper rich, and silver rich crystals, ie copper
    dissolved in silver, and silver dissolved in copper), and allow
    crystal grain growth to occur.  Both will increase the effectiveness
    of the age hardening procedure.  But I've a problem with these
    instructions. Many of the times I've quenched sterling silver from
    that high a temperature, I get major cracks forming.  In a number of
    pieces I did in grad school, I used that propensity of overheated
    silver to shatter when quenched to get some interesting effects of
    broken and shattered forms.  So the handy book's specification for
    annealing that high then quenching makes me wonder just how they wish
    to do this without destroying the piece...  Still, I mention it for
    what its worth.  

    Hope this helps. 

    Peter Rowe 




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