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Re: [Orchid] Distilled water & Deionized water
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John Burgess Saturday, June 09, 2001
   
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>     Could someone help me in understanding the properties of distilled
>     water and deionized water? Someone I spoke with said that deionized
>     water was corrosive.  It would seem to me that it would be less
>     corrosive since it doesn't contain the ions or minerals that other
>     water has.  Enlighten me.


    G'day;  Distilled water might contain small amounts of other volatile
    substances, but very little minerals.  For instance if one distils
    say, beer, without the elaboration of special fractionating columns,
    the distillate will contain water of course, but also ethyl alcohol,
    ethyl acetate, butyl alcohol, and so on - a whole swag of small
    amounts of other volatile substances.  Thus distilled tap water will
    contain a small amount of volatile contaminants, but will be
    reasonably pure for most purposes. 

    Water is de-ionised by passing it through glass columns containing
    deionising resins, and the output will contain no metal salts, acids
    or alkalis or other substances which ionize when dissolved in water.
    But it may - and probably will - contain substances which do not
    ionize. 

    If extra pure water is required, then distilled water is used to
    dissolve a small amount of potassium permanganate, a little alkali is
    added, and the liquid is boiled and re-distilled using a good
    fractionating (separating) column.  The permanganate oxidizes any
    organic material in the water, and the distillate is very pure. 

    For ultra pure water, the water obtained by re-distillation over
    alkaline permanganate is passed through deionising columns. This will
    also remove carbon dioxide.    BUT! as soon as the water is allowed
    to contact the atmosphere it will start to dissolve carbon dioxide,
    and this will ionize at once.   Water thus containing carbonic acid is
    corrosive; this is how caves are formed in limestone country. 

    I used to work with pure waters at one time, and the ionization is
    measured by passing a small electric current through it via platinum
    electrodes to measure  resistance.  Distilled water had a resistance
    of 58 thousand ohms per square centimetre of electrode at a distance
    of one centimetre apart.   Deionised water had a resistance of 4
    million ohms. 

    For most purposes, either distilled or deionised water is
    satisfactory.  

    If  pure water is wanted, then don't get it from a garage,( who sells
    it to top up batteries.) Many tend to fill the bottle with either tap
    or rain water. I have proved this! Get either distilled water or
    deionised water from the local pharmacy.  If you need a lot, then get
    a deionising unit from a laboratory supplier, or from a specialist in
    purifying water.  Most photographic processing labs use deionised
    water, and have a small unit on the premises. -Yes, I know it's a bit
    long - but you did ask to be enlightened! Cheers -- John Burgess;  
    johnb AT ts.co.nz of Mapua Nelson NZ  



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